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The Lunar Priestess; in sharp contrast with Himeko, Chikane is a very commanding girl of the same age. She has a very noble and elegant aura, lives in a large mansion with many maids, and is considered to be of the highest standing at their school; she has a considerable fan following of both genders and is the frequent target of love confessions.
Chikane is also exceptionally skilled in the areas of tennis and, more significantly, the piano; she apparently enjoys playing for Himeko, who enjoys listening to her perform. Many at school believe she has a relationship with Sōma, though this is proven to be untrue. She has been in love with Himeko since they first met, although she does not reveal it until much later, all the while hiding her jealousy and hurt at the sight of Himeko and Sōma together. Her feelings for Himeko soon borders upon obsession – she wants to complete the Ame no Murakumo summoning ritual quickly so that she alone can protect Himeko (and hence not requiring Sōma's assistance in the process). She eventually appears to "turn evil", vanquishing all but two of the other Orochi heads and assuming their place after attacking and sexually assaulting Himeko in an effort to force Himeko to be malevolent to Chikane. The truth behind her actions is more complex than at first meets the eye. However, even though Chikane turned away from evil once to save Himeko, she is about to learn that the darkness will forever dominate her destiny. Chikane carries the lunar symbol on her back.